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Preheat oven to 180 degrees Celsius (350 F). Line a brownie tin with baking paper and set aside.
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In a microwave safe bowl, melt the butter for 1 minute or until completely melted.
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Add the baking cocoa and coffee to the butter and whisk together until smooth and combined.
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Add the sugars, eggs and vanilla essence to the bowl and stir to combine.
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Add baking powder, salt and flour and stir until just combine. Be careful not to overmix.
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Pour the brownie mixture into the brownie tin, ensuring that it is spread evenly and smooth. Layer 12 Oreos evenly over the brownie batter in a single layer.
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Place in the oven and bake for 18-20 minutes, or until just set and a toothpick inserted into the centre comes out clean. Remove from oven and set aside to cool.
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Meanwhile, crush 1.5 packs of the remaining Oreos in a food processor, or with your hands if you don’t have one. Pulse/crush until it becomes a coarse crumb.
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In a large microwave safe bowl, add the marshmallows and butter. Heat in the microwave for 90 seconds, and remove from the microwave. Stir to combine with a plastic spatula (otherwise the marshmallow will stick).
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Pour the Oreo crumbs into the bowl with the marshmallow mix and stir to combine.
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Once your brownies are out of the oven and have cooled slightly, pour the marshmallow mix over the brownies, using a plastic spatula to smooth the marshmallow mix evenly over the top of the brownies.
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Crumble the remaining Oreos over the top, pressing them gentle into the marshmallow mixture to make them stick.
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Allow the brownies to cool completely before cutting, or place in the fridge overnight before serving.