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In the bowl of your stand mixer with the paddle attachment (or a large bowl with a hand held mixer), cream the butter, brown sugar and white sugar together on a medium speed until combined.
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On a low speed, add the peanut butter, egg and vanilla to the butter and sugar. Turn the speed to high and beat the mixture until light and smooth.
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With the mixer speed on low, pour in the flour, baking powder and salt and mix until combined completely, scraping any additional flour down from the sides with a spatula.
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Cover with glad wrap and chill the cookie dough for at least 1 hour. When you are ready to bake, remove from the fridge.
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Preheat the oven to 180C (350F), and line a tray with baking paper.
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Take 1 tablespoon of dough and roll into a ball, then place on the baking tray. Get one piece of the cooking chocolate and push into the dough ball, making a sort of cradle. Take another 1 tablespoon of dough and roll into a ball, and top the dough ball with the chocolate with the second dough ball. Seal down the sides so the chocolate is completely covered, and roll in your hand to make a smooth ball.
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Repeat until you have no more remaining dough, which should make about 12 cookies.
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Bake the cookies in the oven for 10-11 minutes, or until the cookies are lightly browned. Allow to cool on the baking tray for around 10 minutes and transfer to a wire rack to cool completely.
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Serve warm or keep in an air tight container for up to 7 days.